Product ID:MANGANOUS SULFATE MONOHYDRATE, M113
MSDS Date:07/31/1992
FSC:6810
NIIN:00N037634
MSDS Number: CBCBB

FISHER SCIENTIFIC CHEMICAL

1 REAGENT LN
FAIR LAWN, NJ 07410
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 201-796-7100

Cage: 1B464

FISHER SCIENTIFIC CO. CHEMICAL MFG DIV

FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 1B464

50 MG/KG/DAY. DAILY URINALYSES SHOULD BE DONE

RTECS: 9999999ZZ

UNUSUAL URINARY FINDINGS APPEAR. IV ADMIN IS

RTECS: 9999999ZZ

PRESS. FOR INTRAMUSC ADMIN, GIVE 20% SOLN

RTECS: 9999999ZZ

W/EQUAL VOL OF 1% PROCAINE. DOSE LIMIT IS SAME AS

RTECS: 9999999ZZ

ABSORB MATL & PLACE INTO CNTNRS FOR LATER DISP.

RTECS: 9999999ZZ

DISPOSAL. KEEP UNNEC PEOPLE AWAY. ISOLATE HAZARD

RTECS: 9999999ZZ

PARTICULATE RESP. SUPPLIED-AIR RESP. SCBA. 250

RTECS: 9999999ZZ

AIR RESP W/FULL FACEPIECE, HELMET OR HOOD. SCBA

RTECS: 9999999ZZ

RESP W/HIGH-EFFICIENCY FILTER. TYPE C SUPPLIED-AIR

RTECS: 9999999ZZ

CONTINUOUS-FLOW MODE. 10,000 MG(MN)/M3- TYPE C

RTECS: 9999999ZZ

DEMAND OR OTHER POS PRESS MODE OR WITH FULL

RTECS: 9999999ZZ

& FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

MANGANESE, MONOSULFATE, MONOHYDRATE; (MANGANOUS SULFATE

CAS: 10034-96-5

RTECS: OP0893500

Fraction By Weight: 100%

OSHA PEL 5 MG MN/M3 CEILING

ACGIH TLV: 5 MG MN/M3

COUNTS & INCRD OSMOTIC FRAGILITY OF BLOOD. INGEST

RTECS: 9999999ZZ

WASH IMMED W/LG AMTS OF

RTECS: 9999999ZZ

EVID OF CHEM REMAINS (AT LEAST 15-20 MIN). GET MED

RTECS: 9999999ZZ

ATTN IMMED. IF VOMIT OCCURS, KEEP HEAD LOWER THAN

RTECS: 9999999ZZ

DECISION IF SEVERITY OF POIS REQS ADMIN OF ANTIDOTE

RTECS: 9999999ZZ

PERS. CALCIUM EDETATE IS EFTIVE IN REMOVING

RTECS: 9999999ZZ

STAGES OF MANGANISM. ADMIN OF CALCIUM DISODIUM

RTECS: 9999999ZZ

SOLN. GIVE 15-25 MG/KG (0.80-0.125 ML OF 20% SOLN/KG

RTECS: 9999999ZZ

HR PERIOD TWICE DAILY. MAX DOSE SHOULD NOT EXCEED

RTECS: 9999999ZZ

REST PERIOD OF @ LEAST 2 DAYS BETWEEN COURSES.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL:10,000PPM (MN) IMMED
DANGEROUS TO LIFE/HLTH. MAY CAUSE COUGH, CHOKING & TRACHEAL IRRIT.
SKIN:NO DATA AVAIL; MAY CAUSE IRRIT. EYES:DIRECT CNTCT MAY CAUSE
IRRIT & LACRIM. INGEST:MANGANESE S ALTS ARE POORLY ABSORBED BUT MAY
CAUSE GASTRITIS, NAUS, DIARR & HYPOGLYCEMIA. CHRONIC:MAY CAUSE
HDCH, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:RESTLESS SLEEP, DROW, IRRITABILITY,
DIZZ, HYPOTENSION, PATHOLOGIC LAUGHTER/GIDD, CONVLS, VISUAL
HALLUCINATIONS, DOUBLE VISION, IMPAIRED HEARING, UNCONTROLABLE
IMPULSES, MENTAL CONFUSN, EUPHOR IA, EXCESS SALIVATION, CHILLS,
FEVER, ACHING MUSCS, MOUTH & THROAT DRYNESS, BRONCH & PNEUM &
IMPOTENCE. AFTER (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:REMOVE TO FRESH AIR IMMED. IF BRTHG HAS STOPPED,
PERFORM ARTF RESP. KEEP WARM & @ REST. TREAT SYMP & SUPPORTIVELY.
GET MED ATTN IMMED. SKIN:REMOVE CONTAMD CLTHG & SHOES IMMED. WASH
AREA W/SOAP O R MILD DETERGENT & LG AMTS OF WATER UNTIL NO EVID OF
CHEM REMAINS (AT LEAST 15-20 MIN). IN CASE OF CHEM BURNS, COVER
W/STERILE, DRY DRESSING. BANDAGE SECURELY BUT NOT TOO TIGHTLY. GET
MED (ING 3)

Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR
REGULAR FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG OR REGULAR
FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROTECTIVE
EQUIPMENT . NO ACUTE HAZARD. MOVE CNTNR FROM FIRE AREA IF POSSIBLE.
AVOID BRTHG VAPS/DUST; KEEP UPWIND.
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME.

Spill Release Procedures:KEEP COMBUSTS (WOOD, PAPER, OIL, ETC) AWAY
FROM SPILLED MATL. DO NOT TOUCH SPILLED MATL. FOR SM DRY SPILLS
W/CLEAN SHOVEL PLACE MATL INTO CLEAN, DRY CNTNR & COVER; MOVE
CNTNRS FROM SPILL AREA. FOR SM LIQ SPILLS, TAKE UP W/SAND,
EARTH/OTHER(ING 16)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:USE NIOSH/MSHA APPRVD RESPS . AS DUST/MIST: 25
MG(MN)/M3- DUST & MIST RESPS, EXCEPT SINGLE USE. 50 MG(MN)/M3- DUST
& MIST RESPS, EXCEPT SINUE USE & QUARTER-MASK RESPS. AS DUST,
MIST/FUME: 50 MG( MN)/M3- FUME OR HIGH-EFFICIENCY (ING 18)
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION AND/OR GENERAL DILUTION
VENTILATION TO MEET PUBLISHED EXPOSURE LIMITS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 23)
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
APPROP PROT (IMPERVIOUS) CLTHG & EQUP TO PVNT POSSIBILITY OF SKIN
CNTCT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP: PRLNGD PERIOD OF TIME, SYMPS OF PARKINSONS' DISEASE
MAY APPEAR; INCLS MASK-LIKE FACIAL EXPRESSIONS, MUSC WEAK &
RIGIDITY, SALIVATION, TREMORS OF UPPER EXTREMS & HEAD, STAG &
SLURRED S PEECH. MAY ALSO CAUSE LIVER, KIDNEY & PERM BRAIN DMG.
OTHER SYMPS MAY INCL LEUCOPENIA, ELEVATED ERYTHROCYTE (ING 2)

Melt/Freeze Pt:M.P/F.P Text:135F,57C
Spec Gravity:2.9
Appearance and Odor:PALE RED, SLIGHTLY EFFLORESCENT CRYSTALS.

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND
PRESSURES. AVOID HEATING TO DECOMPOSITION.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE
TOXIC OXIDES OF SULFUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS .

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particular situation.